I was mostly interested in [DC pumps] for the energy savings and the improved safety of low voltage dc. But now that I know [DC pumps] are actually AC and that low voltage can't (as far as I know) be protected by GFCI, that only leaves us with efficiency.
I am also not an expert on safety matters with electricity in ponds, nor am I an electrical engineer. I'm that guy with a little knowledge and too much confidence. So read on at your own risk!
TL/dr: 1) The DC pump is likely to be safer than an AC pump of the same capacity
2) You can buy a DC GFCI, though I don't know how easy they are to install/use
GENERAL POINTS:
There are two things to consider: the amount of current you are exposed to, and the frequency that the current is changing at. More current == bigger effect on muscles and cardiac pacemakers (the pacemakers your are born with, not the manmade ones!). A little current is no problem (you can feel it, maybe it hurts/burns, but otherwise does not harm you), but as you increase the current, at some point you interfere with the heart.
For 'house current', at around 10-20 mA your muscles contract so that you cannot let go. Around 40-100 mA is enough to cause cardiac issues.
DC VERSUS HOUSE CURRENT:
How does DC compare with house current?
First, house current is 120 volts RMS, which is 5-10 times the voltage of a 12v or 24v DC system. With higher voltage you can drive larger currents, so this makes the DC system safer than the AC system.
Second, muscles and pacemakers respond more strongly (are more sensitive) to 60 Hz pulsating current than continuous current. The effect is big -- a factor of 3 to 5. So this also makes DC systems safer than house current, which is 60 Hz AC.
(These values are repeated in many locations across the web, often without any citation provided. Here is a publication that gives references; I have not looked them all up, but they seem reliable:
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2763825/
DC MOTOR VS AC MOTOR:
A DC motor reverses the current direction in order to drive the motor. Does this negate the DC advantage? No.
If the current leak occurs 'upstream' of this reversal, than you are exposed to DC, not AC -- the DC system retains its advantage.
If the current leak occurs 'downstream' of the reversal, then you still have the advantage that the voltage is lower.
I am not sure at what rate the DC current in the particular DC pumps we are discussing is switched at. Many DC motors are switched at very high rates, substantially over 1 KHz. At these frequencies of modulation (e.g., 5 KHz), the thresholds for muscle contraction and cardiac arryhmias are roughly comparable to DC. So the DC motor retains its safety advantage over the AC motor.
DC GFCIs:
Are there DC GFCI's? Yes, absolutely. The general principle -- is the amount of current flowing in the two conductors equal, or is more current going out than is coming back -- can be applied to AC or DC. Of course, you cannot use a GFI designed for AC on a DC circuit.
And I cannot speak to the cost or ease of installation of DC GFIs. But they definitely exist!
For more information about GFCI's, see:
https://www.westernautomation.com/wp-content/uploads/2016/03/GFCIs_For_AC_DC_Systems.pdf