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Since Copper is present in all water, my question would be: Do you know what the current Copper level is in your pond? Would adding a very small amount (remember, we are talking micro-grams for toxicity) increase your present level to a level of concern? Best to be safe!
FYI- 1/4"of Copper tubing will leach, maybe a wee amount, but since Copper accumulates I would have a problem with any addition to the water column.
It almost seems ridiculous that I now just ordered a copper test kit to add to my collection .... Feel like a kid when I had a chemistry set with the 3-4 doors that opened. I've searched the internet and have yet to find a pond fountain made with brass, poly or anything but a copper tube. I'm wondering if we're being over cautious and also wondering if I can't just slip a 3/8" tubing
right down through the copper tubing. I now have the T and all the parts, just hesitancy to run it when I have it hooked up until I have definitive answers.