Ok Charles I'll take up the battern from you here and stick my ten pennys worth in as to what we thinks happening here
Nepen Please answer all I'm asking
In future if your nitrate is high first off test the water coming out of your taps sometimes it can be a problem .
We are talking fish tank here not pond yes ? .... If so it may well be an idea to go online and look up JBL Aquatics products .and buy their answer to high nitrate readings in Aquarium's for any future problems you may get.........
They do a product called nitratex which is a resin that leaches the nitrate from your tanks water.
http://www.jbl.de/en/aquatics-freshwater/detail/1/freshwater-aquatics
However first things first I noticed your talking about your substrate is now being full of a white substance yes? Ok please tell me when removed from the water and squeazed between your fingers does it turn brown and bitty ?
This is caused by food rotting down in your gravel and it has now unfortunately taken over which is the original reason for your Ph crash .
It appears your either not maintaining your tank or your not doing it correctly how do I know about this ???
It's because I've come across this more than once in peoples tanks weve been asked to look at with the same problem.
Next in reality you have to do what is basically the Nuking of your tank, equipment etc
You simply wont get rid of this without stripping your tank down to brass tacks and first off boiling your gravel to get rid of the growth you have thats taken over everything ( this is the best way we discovered of gettinmg rid of it ).... you have to illiminate each and every spore of this
Once you've done this disinfect your tank with Acriflavine this includes all your plant pots getting rid of the filling and making sure all your plants are clear either that or throw them out and buy new ......
Next strip your filter down clean any white stuff that may have got into it then boil the media disinfecting the filter itself making sure it is spotless , all this may sound like over kill but we found its the only way of making sure it stay's away permanently.
Next re introduce your fish slowly putting a sacrificial fish in the tank to help kick start your biological filtration again , when this has happened add the rest or do a dry cycle
The only way to stop this happening in the future is to put into place a maintenance routine that includes the syphoning of your gravel regular filter maintenance and regular water changes also look at your feeding regieme removing any food thats not been eaten.
Dave