Your KH is definitely a problem. The crushed limestone would help, but it may take some time to dissolve it enough to be beneficial. I suspect you are having pH swings from morning to night. That puts a lot is stress on your fish.
I, like many others, use baking soda to raise the KH. It will also raise the pH, which yours need to do. The pH at 6.5 is acidic and your beneficial bacteria will have trouble living in that water.
You need to raise the KH gradually over a few days to keep from adding even more stress to the fish. The pH will rise as well, but if that is a gradual rise it will not be a problem.
My KH is kept around 200 or more ppm. That is where my filters work their best. The pH is always at 8.2 or 8.3 and stable. That level is not a problem for the fish. The fluctuating pH is the problem. It doesn't need to be a specific number, but it should not be acidic as yours is.
I would start raising that KH asap. Just go slowly and test often to make sure you aren't raising it too fast. With your water, you will probably need to boost the KH whenever you do a water change.
Also, since rain is acidic, it can affect the KH. I boost mine whenever we are expecting heavy rain.