The nibbling could be confused with bumping. Spawning behavior would be one or more fish (normally smaller) following a female. The males normally are below and near the back end of the female or right behind. That's how it starts. Can go on for several days like that. The males may only follow for a few second, a few minutes, and then stop and repeat later. The female produces a chemical that attracts the males. As the female produces more the males can get more interested, start bumping the back of the female, swimming can be more intense. That can go on for a bit. At some point the males decide it's time and start pushing the female in all kinds of directions, hopefully into weeds where the deed takes place. Without the weeds this pushing can get to be a lot. The female get tired, sometimes can't swimming and the males continue to push her and now she's completely defensive.
Nibbling in Koi you should be able to see them extend their mouth. Bumping is more of a side and top of the head thing.
This often happens just after dawn in the spring, but can happen any time. Water changes can trigger spawning to. In the wild their ancestors swam up small ditches and creeks after a rain.
It is common for no eggs to survive, or few fry to hatch and live very long. Depends on the pond, hiding spots, food.
Here's the web page I made for you on Water Quality. Kind of a draft, but hopefully some use.