Update: Firstly we have a bad earth from the house, this is causing "controlled" stray voltage to follow the course of least resistance which is the pond. We also get a smaller voltage from a smaller pond. Most households have controlled voltage from computer equipment or smart devices, even cookers. This voltage would normally follow the correct earth route through the spike in the ground near the consumer unit, but as our wiring to the spike appears faulty this is creating resistance and creating backflow to all earth points throughout the house. The pond just happens to get the worst of it due to the body of water creating a more favourable earth.
We have an electrician fixing the earth asap but obviously keeping an eye on the surge voltage protection for personal safety until it's fixed. The surge protection in house will also protect the fish in the pond but is a one time deal and needs replacing if it kicks in.
To get over the problem with backflow to the pond so I can get the filters running again we will be putting a new earth spike near our shed and wiring our sockets from that. Live and neutral will come direct from the house. I'll then test to make sure the situation isn't being made any worse by picking up other localised voltages but I should get a zero reading before activating main pump. Anything else will be inductive charge which we can't avoid unless we use external pumps.
Once the bad earth is sorted, either by adding a secondary linked spike and or replacing the earth wire to the existing spike, we'll check from backflow again and take it from there.
Hope this helps anyone else getting a similar problem