Silver tarnished from pond water?

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OK so I spent about 40 minutes bare-legged in my pond getting rid of the darn blanket weed. When I got our and washed off I noticed my two toe rings which are silver were both tarnished a brassy colour.
Anyone any idea why this would be and what could cause it, please?
I know bleach makes silver go black but this was brassy
 
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100% had them on my tootsies for many years! It was very strange
 

JRS

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Suspect it has something to do with the acidity or possibly sulfides in the pond water.

 

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