When I first started in the hobby I got a used tank that was sitting in someone’s closet for years. I used all the water conditioner it came with and after months of use in a goldfish tank I realized it was like 2 years expired. Granted I never tested my water back then but fancy goldfish are somewhat delicate and I never had issues. If anything it probably just decreases in effectiveness and doesn’t work as well when it expires.
If a fancy can make it I seriously doubt your koi will be harmed, worse case scenario your water isn’t fully dechlorinated.