The realy small cracks can be sealed by thinning the product until it seeps into the crack. I would not chip away unless you want to make that a trough to hold the thin stuff, then come back with a thicker coat to cover your chiseled out area. I used sand and small rocks in my larger cracks. that allowed me to hide the thoroseal which is a light grey material.
I used a paint brush to apply mine in some areas and putty knife in others, You can also put it into a bag and cut the corner then squeeze it out deep into large cracks.
I had boulders that were too heavy to move but had settled over the years away from each other. My leaks were so massive, the 5200 GPH pump had trouble keeping up with the leaks. This stuff fixed all the gaps and cracks.
It is not cheap. Be prepared to pay about $50 for a #30 lb bag. I don't think you can get any other size.
If you want to prep the surface first, very carefully use muriatic acid (pool acid) to clean the cracks. Muricatic acid is Hydrchloric acid in a weak solution. In small amounts, I wouldn't even worry about nuetralizing it. It will eventually loose its potency especially when the water flows.