I use Prime for my water changes (or adding water) I add it right before I start the hose. The amount you use should be enough to treat the entire volume of water in your pond.
My pond is also small, just a bit over 500 gallons. I use 6 capfulls of pond prime which is enough to treat 600 gallons.
These are the directions from Seachem website. Just to verify that total volume should be treated and not just amount of water being added. This is for regular Prime which can be used for a small pond but dosing will be different as it's not as concentrated as the Pond Prime.
Use 1 capful (5 mL) for each 200 L (50 US gallons) of new water. For smaller volumes, please note each cap thread is approximately 1 mL. May be added to aquarium directly, but better if added to new water first. If adding directly to aquarium, base dose on aquarium volume. Sulfur odor is normal. For exceptionally high chloramine concentrations, a double dose may be used safely. To detoxify nitrite in an emergency, up to 5 times normal dose may be used. If temperature is > 30 °C (86 °F) and chlorine or ammonia levels are low, use a half dose.
You can read more here:
https://www.seachem.com/prime.php